Multi-step rearrangement mechanism for acetyl cedrene to the hydrocarbon follower

Screenshot_2021-03-24-Multi-Step-Rearrangement-Mechanism-for-Acetyl-Cedrene-to-the-Hydrocarbon-Follower†-

Conversion of acetyl cedrene (2) to its follower (3) using acetic anhydride and polyphosphoric acid involves a multi-step cationic molecular rearrangement, which is consistent with deuteriation and 1-13C labeling studies of acetyl cedrene. The key step involves cyclopropylcarbinyl cation-cyclopropylcarbinyl cation rearrangement.

The paper can be purchased from this link: https://link.springer.com/article/10.1007/s10600-017-2085-1?no-access=true

 
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